W. Masuda et al., NUMERICAL-SIMULATION OF A SUPERSONIC-FLOW CHEMICAL OXYGEN-IODINE LASER SOLVING NAVIER-STOKES EQUATIONS, JSME international journal. Series B, fluids and thermal engineering, 40(1), 1997, pp. 87-92
The reaction zone structure of a supersonic flow chemical oxygen-iodin
e laser (COIL) is simulated solving the two-dimensional Navier-Stokes
equations in order to clarify the reaction zone structure and the effe
cts of water vapor condensation precisely. A chemical kinetic model co
nsisting of 10 chemical species and 21 chemical reactions is used to d
etermine the chemical composition of the mixture. The liquid phase is
modeled as a number of droplet classes. Each class contains only dropl
ets of a certain range of sizes, which is approximated as one average
size. The calculation shows that the I-2 gas injected into the singlet
oxygen through a two-dimensional slit mixes very slowly and the small
signal gain coefficient is high only in a narrow layer where the mole
fraction of I(P-2(1/2)) reaches a high value. Nonequilibrium condensa
tion takes place during supersonic expansion, generating water droplet
s whose size is much smaller than the wave length of COIL. Condensatio
n reduces the small signal gain coefficient, since the temperature ris
e caused by latent heat suppresses the generation of I(P-2(1/2)).