QUANTITATIVE FLUORESCENCE EXAFS ANALYSIS OF CONCENTRATED SAMPLES - CORRECTION OF THE SELF-ABSORPTION EFFECT

Authors
TROGER L ZSCHECH E ARVANITIS D BABERSCHKE K
Citation
L. Troger et al., QUANTITATIVE FLUORESCENCE EXAFS ANALYSIS OF CONCENTRATED SAMPLES - CORRECTION OF THE SELF-ABSORPTION EFFECT, JPN J A P 1, 32, 1993, pp. 144-146
Citations number
8
Categorie Soggetti
Physics, Applied
Journal title
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS → ACNP
Volume
32
Year of publication
1993
Supplement
32-2
Pages
144 - 146
Database
ISI
SICI code
Abstract
The EXAFS amplitudes of concentrated samples measured in the fluoresce nce mode strongly depend on the detection geometry through the self-ab sorption effect. Knowing the stoichiometry of the sample, we can fully correct for the self-absorption effect using a simple theory and obta in the true EXAFS. The correction procedure presented here for the Oxy gen K-edge EXAFS of NiO is generally applicable and should be the firs t step in the quantitative analysis of fluorescence EXAFS data of conc entrated samples.