EXAFS is a useful probe of studying the local structure of disordered
systems. We have developed a new sample cell and carried out EXAFS mea
surements for liquid semiconductors such as Se, Te and As2Se3, whose e
lectronic properties often show metallic behaviour at high temperature
s and pressures. EXAFS has been found to give useful information on th
e neighboring configuration around a central atom as long as the atoms
are covalently bonded.