Inelastic electron scattering provides a convenient, lab-based alterna
tive to bremsstrahlung or synchrotron radiation X-ray spectroscopy for
inner-shell excitation studies of gases, solids and surfaces. The cur
rent capabilities of inner-shell electron energy loss spectroscopies (
ISEELS) are reviewed and compared to X-ray techniques. Issues discusse
d include: momentum transfer dependence, oscillator strength determina
tion, spatial and energy resolution, orientational sensitivity. Exampl
es are given of the application of EELS to gases, solids and surfaces.