The X-ray resonance exchange scattering (XRES) has been measured at th
e Nd L2,3-edges on the 330, 440 and 550 Bragg reflections in a ferroma
gnetic Nd2Fe14B single crystal. The XRES results at the L2-edge reflec
t the spin polarization of unoccupied 5d-bands of Nd due to electric d
ipole transitions. Those at the L3-edge show the possibility of electr
ic quadrupole transitions to the highly localized 4f-states. The tempe
rature dependence of XRES confirms the sensitivity to the local magnet
ic moment of specific site. The magnetic moments of Nd 4f and 4g sites
rotate from