XANES STUDY OF DOPING AND REDOX MECHANISMS FOR HOLE CREATION IN BI(2212) SUPERCONDUCTING SYSTEM

Citation
Kb. Garg et al., XANES STUDY OF DOPING AND REDOX MECHANISMS FOR HOLE CREATION IN BI(2212) SUPERCONDUCTING SYSTEM, JPN J A P 1, 32, 1993, pp. 599-601
Citations number
13
Categorie Soggetti
Physics, Applied
Volume
32
Year of publication
1993
Supplement
32-2
Pages
599 - 601
Database
ISI
SICI code
Abstract
A complete set of polarised XAS spectra at Cu L3 and Bi L3- edges have been recorded on a well characterised single crystals of Bi2Sr2CaCu2O 8+ superconductor. The Cu L3 spectra shows an energy difference of 400 meV between z(3d3z2-r2) and x,y(3dx2-y2) components, with a significa nt intensity in E parallel-to c polarisation. The Bi L3-edges show cle arly the energy shift of superconductor spectra towards low energy wit h respect to Bi(III) references confirming again the Bi-O layers as el ectron reservoir.