S. Chibowski, ZETA-POTENTIAL AND THICKNESS OF A POLYMER ADSORBED LAYER IN THE SYSTEM DISPERSED SOLID-ELECTROLYTE, Polish Journal of Chemistry, 67(6), 1993, pp. 1137-1143
The influence of polyvinyl alcohol (PVA) and polyacrylamide (PAM) on t
he electrokinetic potential of TiO2 and polystyrene latex was studied.
The presence of the polymeric substances leads to a change in the str
ucture of the electric double layer. This in the changes of the zeta p
otential and of the isoelectric point. is reflected upon. The kind and
the number of the functional groups in the polymer macromolecules inf
luence essentialy the above changes. The thickness of the adsorbed lay
er (delta(E)) has been determined from the electrokinetic measurements
. Its value is smaller than that determined from the viscosity measure
ments (delta(H)).