Kj. Randall et al., PHOTON ENERGY-DEPENDENCE OF THE HIGH RESOLUTION-C 1S PHOTOELECTRON-SPECTRUM OF CO IN THE THRESHOLD REGION, Physical review letters, 71(8), 1993, pp. 1156-1159
The C 1s photoelectron spectrum of CO has been measured with high reso
lution in the threshold region. The data exhibit hitherto unresolved v
ibrational structure on the C 1s main photoelectron line as well as ne
w features in the satellite region. The vibrational energy of the COion is 301 +/- 3 meV. The vibrational structure changes dramatically w
ith photon energy due to the influence of the sigma shape resonance.
The new satellite lines which are not present at high photon energies
are attributed to conjugate shakeup processes.