W. Daum et al., IDENTIFICATION OF STRAINED SILICON LAYERS AT SI-SIO2 INTERFACES AND CLEAN SI SURFACES BY NONLINEAR-OPTICAL SPECTROSCOPY, Physical review letters, 71(8), 1993, pp. 1234-1237
Optical second-harmonic and sum-frequency spectra of clean and oxidize
d Si(100) and Si(111) samples reveal a strong resonance band at 3.3 eV
photon energy. It is concluded that the resonance arises from direct
transitions between valence and conduction band states in a few monola
yers of strained silicon at the Si-SiO2 interface and at the selvedge
of clean reconstructed silicon surfaces.