Sb. Desu et Ik. Yoo, TIME-DEPENDENT DIELECTRIC-BREAKDOWN IN BATIO3 THIN-FILMS, Journal of the Electrochemical Society, 140(9), 1993, pp. 120000133-120000135
Electrical degradation followed by breakdown was studied for BaTiO3 th
in films. A field-assisted thermal breakdown was observed which is rel
ated to Poole-Frenkel emission. A semiquantitative electrical degradat
ion/breakdown model is proposed on the basis of Poole-Frenkel emission
and oxygen vacancy behavior during degradation. It is suggested that
accumulation of oxygen vacancies at the cathode and acceptors at the a
node forms a forward p-n junction which increases current leading to r
esultant breakdown.