GENERATION OF THIOSULFINES BY DITHIATION OF DIARYLMETHYLENETRIPHENYLPHOSPHORANES

Authors
OKUMA K SHIMASAKI M KOJIMA K OHTA H OKAZAKI R
Citation
K. Okuma et al., GENERATION OF THIOSULFINES BY DITHIATION OF DIARYLMETHYLENETRIPHENYLPHOSPHORANES, Chemistry Letters, (9), 1993, pp. 1599-1602
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1993
Pages
1599 - 1602
Database
ISI
SICI code
0366-7022(1993):9<1599:GOTBDO>2.0.ZU;2-6
Abstract
Reaction of phosphonium ylides with excess sulfur afforded the corresp onding thiosulfines, which were trapped with maleic anhydride to give the corresponding cycloadducts (1,2-dithiolanes) in good yields. Inter mediary thiosulfines were also formed by sulfurization of thiobenzophe nones with elemental sulfur to give the 1,2-dithiolanes in moderate yi elds.