H. Sunamura et al., LUMINESCENCE STUDY ON INTERDIFFUSION IN STRAINED SI1-XGEX SI SINGLE QUANTUM-WELLS GROWN BY MOLECULAR-BEAM EPITAXY/, Applied physics letters, 63(12), 1993, pp. 1651-1653
Optical investigation of interdiffusion at Si1-xGex/Si heterointerface
s has been performed for the first time in strained Sil-xGex/Si single
quantum wells (SQWs). Photoluminescence (PL) peak energy blue shift o
f up to 22 meV due to interdiffusion-induced potential profile modulat
ion was observed after annealing in vacuum. The diffusion coefficients
obtained were found to closely follow an Arrhenius behavior with an a
ctivation energy of 2.47+/-0.4 eV. Dramatic increase in the integrated
PL intensity was observed in the annealed samples, as a result of the
elimination of effective nonradiative centers. Strain relaxation was
hardly observed even after 900-degrees-C annealing, indicating the unp
recedented structural stability of SQWs in contrast to rather vulnerab
le thick alloy layers. Anomalous peak red shift, probably due to surfa
ce oxidation, was observed by annealing in N2 ambient.