POLYMERIZATION OF ETHENE BY THE NOVEL TITANIUM COMPLEX [TI(ME(3)SINCH(2)CH(2)NSIME(3))CL-2] - A METALLOCENE ANALOG

Authors
TINKLER S DEETH RJ DUNCALF DJ MCCAMLEY A
Citation
S. Tinkler et al., POLYMERIZATION OF ETHENE BY THE NOVEL TITANIUM COMPLEX [TI(ME(3)SINCH(2)CH(2)NSIME(3))CL-2] - A METALLOCENE ANALOG, Chemical communications, (23), 1996, pp. 2623-2624
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
23
Year of publication
1996
Pages
2623 - 2624
Database
ISI
SICI code
1359-7345(1996):23<2623:POEBTN>2.0.ZU;2-L
Abstract
Reaction of the trimethylsilylated diamine ligand (Me(3)-Si)NHCH2CH2NH (SiMe(3)) with titanium(IV) precursors affords the novel distorted-tet rahedral complex [Ti(Me(3)-SiNCH(2)CH(2)NSiMe(3))Cl-2] which, when act ivated by methylaluminoxane, is an active ethene polymerisation cataly st.