T. Nakano et al., TRANSIENT 2D-IR CORRELATION SPECTROSCOPY OF THE PHOTOPOLYMERIZATION OF ACRYLIC AND EPOXY MONOMERS, Applied spectroscopy, 47(9), 1993, pp. 1337-1342
Transient two-dimensional infrared (2D IR) correlation spectroscopy co
upled with real-time Fourier transform infrared (RT FT-IR) measurement
was used to analyze the reaction processes of photopolymerization sys
tems. Unlike the previously developed 2D IR methods based on sinusoida
lly varying IR signals, a newly developed 2D correlation formalism app
licable to transient spectroscopic signals having an arbitrary wavefor
m was used. By this method, features associated with spectral intensit
y changes and peak shifts arising from polymerization reactions were c
learly observed.