ONE-STEP SYNTHESIS OF VINYL CHLORIDE-VINYL ACETATE-OLEFIN TERPOLYMERSON ORGANOMETALLIC INITIATORS

Citation
Df. Grishin et al., ONE-STEP SYNTHESIS OF VINYL CHLORIDE-VINYL ACETATE-OLEFIN TERPOLYMERSON ORGANOMETALLIC INITIATORS, Journal of applied chemistry of the USSR, 65(8), 1992, pp. 1539-1543
Citations number
11
Categorie Soggetti
Chemistry Applied
ISSN journal
0021888X
Volume
65
Issue
8
Year of publication
1992
Part
2
Pages
1539 - 1543
Database
ISI
SICI code
0021-888X(1992)65:8<1539:OSOVCA>2.0.ZU;2-J
Abstract
An initiator consisting of a trialkylboron and organometallic peroxide was used for the one-step synthesis of vinyl chloride-vinyl acetate-e thylene and vinyl chloride-vinyl acetate-1-hexene terpolymers at low p ressure (6-20 MPa) and room temperature. The kinetics of this reaction and some of the physicochemical properties of the copolymers obtained were studied.