Df. Grishin et al., ONE-STEP SYNTHESIS OF VINYL CHLORIDE-VINYL ACETATE-OLEFIN TERPOLYMERSON ORGANOMETALLIC INITIATORS, Journal of applied chemistry of the USSR, 65(8), 1992, pp. 1539-1543
An initiator consisting of a trialkylboron and organometallic peroxide
was used for the one-step synthesis of vinyl chloride-vinyl acetate-e
thylene and vinyl chloride-vinyl acetate-1-hexene terpolymers at low p
ressure (6-20 MPa) and room temperature. The kinetics of this reaction
and some of the physicochemical properties of the copolymers obtained
were studied.