Charge injection leading to catastrophic breakdown has been used to st
udy the dielectric properties of the buried oxide layer in silicon imp
lanted with high-energy oxygen ions. Current versus gate bias, current
versus time, and capacitance versus gate bias were used to characteri
ze, at various temperatures, MOS metal-oxide-semiconductor capacitors
with areas in the 1 X 10(-4)-1 X 10(-2) cm2 range fabricated with comm
ercially available single- or triple-implant separation by implanted o
xygen silicon wafers. The data show that injected charge accumulates i
n the buried oxide at donorlike oxide traps ultimately leading to cata
strophic breakdown. Both Poole-Frenkel and Fowler-Nordheim conduction,
as well as impact-ionization mechanisms, have been identified in the
oxide. The charge and field to breakdown in the best buried oxides are
, respectively, near 1 C cm-2 and 10 MV cm-1, similar to the thermally
grown oxide parameters. Cumulative distributions of these parameters
measured over a large number of capacitors show that the frequency of
breakdown events caused by extrinsic defects is scaled with the capaci
tor area. Intrinsic and extrinsic defect distributions are broader tha
n with thermally grown oxides.