TI COMPOUNDS WITH FULVALENE BRIDGES - THE STRUCTURE OF [CPTIME2]2(C10H8)

Authors
WOHRLE T THEWALT U
Citation
T. Wohrle et U. Thewalt, TI COMPOUNDS WITH FULVALENE BRIDGES - THE STRUCTURE OF [CPTIME2]2(C10H8), Journal of organometallic chemistry, 456(2), 1993, pp. 30000021-30000023
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
456
Issue
2
Year of publication
1993
Pages
30000021 - 30000023
Database
ISI
SICI code
0022-328X(1993)456:2<30000021:TCWFB->2.0.ZU;2-S
Abstract
X-ray analysis for the orange-yellow thermally unstable crystalline co mpound [CpTiMe2]2(C10H8) (3(Me)), which results from methylation of [C pTiCl2]2(C10H8), confirms the presence of a fulvalene bridge. The two CpTiMe2 fragments in 3(Me) are trans with respect to the fulvalene gro up.