STUDY OF EXCESS VOLUME OF MIXING FOR THE BINARY-MIXTURES OF ACRYLONITRILE WITH CYCLOHEXANE, BENZENE, P-XYLENE AND MESITYLENE

Authors
YADAVA RR YADAVA SS
Citation
Rr. Yadava et Ss. Yadava, STUDY OF EXCESS VOLUME OF MIXING FOR THE BINARY-MIXTURES OF ACRYLONITRILE WITH CYCLOHEXANE, BENZENE, P-XYLENE AND MESITYLENE, Revue Roumaine de Chimie, 38(5), 1993, pp. 533-537
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
38
Issue
5
Year of publication
1993
Pages
533 - 537
Database
ISI
SICI code
0035-3930(1993)38:5<533:SOEVOM>2.0.ZU;2-8
Abstract
Excess volume of mixing (V(E)) for the binary mixtures of acrylonitril e and non-polar solvents viz. cyclohexane, benzene, p-xylene and mesit ylene has been determined pyknometrically over the complete mole fract ion range at 307.4 K. The V(E) values are positive for acrylonitrile cyclohexane system, negative and more neptive for acrylonitrile + ben zene and acrylonitrile + p-xylene systems respectively. The values of V(E) are less negative in the acrylonitrile + mesitylene system. The r esults are discussed in terms of molecular interactions governed by in duction and steric effects.