A 14-year (1977-1990) record of global solar radiation measurements pe
rformed in Athens, Greece, has been utilized to determine the distribu
tion of radiant energy in the various wavelength bands. The monthly me
an values of the irradiation ratios in the spectral intervals, blue (0
.380-0.525 mum), green-orange (0.525-0.630 mum), red (0.630-0.710 mum)
, and photosynthetically active radiation (PAR) (0.380-0.710 mum) and
the global irradiation (0.3-2.8 mum) compare favourably with values re
ported in the literature for different locations over a wide geographi
cal area. The irradiation ratios exhibit seasonal variations attributa
ble to changes in local air-mass climatology. It is observed that the
proportion of the radiant energy in the various spectral bands relativ
e to the global solar irradiation increases as sky conditions change f
rom 'clear' to 'partly cloudy'. Finally, the observed seasonal depende
nce of the broad-band spectral energy distribution is essentially caus
ed by changes in the composition of the air masses (turbidity, airborn
e pollutants, clouds) in residence at the measurement site in the cour
se of the year.