Tm. Letcher et Jd. Mercerchalmers, PARTIAL MOLAR VOLUMES OF CRYPTAND-222 IN ORGANIC-SOLVENTS AT 25-DEGREES-C, Journal of solution chemistry, 22(9), 1993, pp. 851-857
The partial molar volumes at infinite dilution of cryptand-222 (C-222)
in water, methanol, acetonitrile, ethanol, dimethylsulfoxide, propano
l, 2 propanol, chloroform, benzene, 1-butanol, cyclohexane, butyl-meth
ylketone, hexane, tetrahydronaphthalene, heptane, octane, cyclohexyl-b
enzene and decane were measured at concentrations ranging from 0.01 to
0.1 mol-L-1 at 25-degrees-C. The partial molar volumes at infinite di
lution showed remarkable dependency on the molar volume of the solvent
. The partial molar volumes at infinite dilution for C-222 increase as
the solvent molar volume increases.