FACTORS INFLUENCING THE STEREOSELECTIVITY IN THE CYCLOADDITION OF IMINO-DIENOPHILES DERIVED FROM AMINO ETHERS, AMINO-ALCOHOLS, AND AMINO-ACID ESTERS

Authors
DEVINE PN REILLY M OH T
Citation
Pn. Devine et al., FACTORS INFLUENCING THE STEREOSELECTIVITY IN THE CYCLOADDITION OF IMINO-DIENOPHILES DERIVED FROM AMINO ETHERS, AMINO-ALCOHOLS, AND AMINO-ACID ESTERS, Tetrahedron letters, 34(37), 1993, pp. 5827-5830
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
37
Year of publication
1993
Pages
5827 - 5830
Database
ISI
SICI code
0040-4039(1993)34:37<5827:FITSIT>2.0.ZU;2-U
Abstract
Imino dienophiles derived from amino ethers, amino alcohols and amino esters undergo Lewis acid promoted cycloaddition with Danishefsky's di ene. Cyclic chelation between the imine and oxygen atom increases the stereoselectivity of the reaction.