A NOVEL SYNTHESIS OF CYANOALKYNES VIA IODIDE-CATALYZED CYANATION OF TERMINAL ACETYLENES WITH CUPROUS CYANIDE

Authors
Citation
Ft. Luo et Rt. Wang, A NOVEL SYNTHESIS OF CYANOALKYNES VIA IODIDE-CATALYZED CYANATION OF TERMINAL ACETYLENES WITH CUPROUS CYANIDE, Tetrahedron letters, 34(37), 1993, pp. 5911-5914
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
37
Year of publication
1993
Pages
5911 - 5914
Database
ISI
SICI code
0040-4039(1993)34:37<5911:ANSOCV>2.0.ZU;2-4
Abstract
Cyanoalkynes were synthesized in fair to good yields from terminal ace tylenes and cuprous cyanide in the presence of trimethylsilyl chloride , water, catalytic amount of sodium iodide, and CH3CN in DMSO at 50-de grees-C.