HIGHLY DIASTEREOSELECTIVE, ENANTIOSELECTIVE CYCLIZATION OF SYMMETRICAL 3,4-DISUBSTITUTED 4-PENTENAL USING CHIRAL RHODIUM(I)-COMPLEX

Authors
WU XM FUNAKOSHI K SAKAI K
Citation
Xm. Wu et al., HIGHLY DIASTEREOSELECTIVE, ENANTIOSELECTIVE CYCLIZATION OF SYMMETRICAL 3,4-DISUBSTITUTED 4-PENTENAL USING CHIRAL RHODIUM(I)-COMPLEX, Tetrahedron letters, 34(37), 1993, pp. 5927-5930
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
37
Year of publication
1993
Pages
5927 - 5930
Database
ISI
SICI code
0040-4039(1993)34:37<5927:HDECOS>2.0.ZU;2-S
Abstract
Concurrent introduction of two chiral centers at 3,4-positions of cycl opentanone from symmetrical 1 was achieved in diastereoselective and e nantioselective fashion by combination of BINAP and cationic Rh(I)(or neutral).