PD2-PROMOTED CYCLIZATION IN TETRACYCLIC DITERPENE SYNTHESIS HIGHLY DIASTEREOSELECTIVE FORMAL TOTAL SYNTHESIS OF (+()-)-STEMODIN/

Authors
TOYOTA M SEISHI T FUKUMOTO K
Citation
M. Toyota et al., PD2-PROMOTED CYCLIZATION IN TETRACYCLIC DITERPENE SYNTHESIS HIGHLY DIASTEREOSELECTIVE FORMAL TOTAL SYNTHESIS OF (+()-)-STEMODIN/, Tetrahedron letters, 34(37), 1993, pp. 5947-5950
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
37
Year of publication
1993
Pages
5947 - 5950
Database
ISI
SICI code
0040-4039(1993)34:37<5947:PCITDS>2.0.ZU;2-A
Abstract
Intramolecular Diels-Alder reaction of the triene 5 and Pd2+-promoted cyclization reaction of the olefinic silyl enol ether of 10 have been utilized as the key steps for a conceptually new, highly diastereocont rolled formal total synthesis of (+/-)-stemodin (1).