BLUE-SHIFT OF THE MIE PLASMA FREQUENCY IN AG CLUSTERS AND PARTICLES

Citation
J. Tiggesbaumker et al., BLUE-SHIFT OF THE MIE PLASMA FREQUENCY IN AG CLUSTERS AND PARTICLES, Physical review. A, 48(3), 1993, pp. 180001749-180001752
Citations number
42
Categorie Soggetti
Physics
Journal title
ISSN journal
10502947
Volume
48
Issue
3
Year of publication
1993
Pages
180001749 - 180001752
Database
ISI
SICI code
1050-2947(1993)48:3<180001749:BOTMPF>2.0.ZU;2-M
Abstract
Photodepletion spectroscopy is used to measure the optical activity of sputtered Ag ionic clusters with up to 70 atoms. With decreasing clus ter size the giant resonance caused by collective excitation of the va lence electrons shifts to higher frequencies. This blue shift is quali tatively explained in terms of a reduced s-d screening interaction in the surface region of the particles.