STUDIES ON CHROMIUM TRIOXIDE-BASED OXIDATIVE COUPLING REAGENTS AND SYNTHESIS OF LIGNAN-CAGAYANONE

Authors
KUO YH LIN ST
Citation
Yh. Kuo et St. Lin, STUDIES ON CHROMIUM TRIOXIDE-BASED OXIDATIVE COUPLING REAGENTS AND SYNTHESIS OF LIGNAN-CAGAYANONE, Chemical and Pharmaceutical Bulletin, 41(9), 1993, pp. 1507-1512
Citations number
13
Categorie Soggetti
Pharmacology & Pharmacy",Chemistry
Journal title
Chemical and Pharmaceutical Bulletin → ACNP
ISSN journal
00092363
Volume
41
Issue
9
Year of publication
1993
Pages
1507 - 1512
Database
ISI
SICI code
0009-2363(1993)41:9<1507:SOCTOC>2.0.ZU;2-B
Abstract
Oxidation of 1-arylprop-1-enes by using the reagent system CrO3-HClO4- CH3CN at 0-5-degrees-C gave seven products from methyl isoeugenol, fiv e from ethyl isoeugenol, four from benzyl isoeugenol, and five from is osafrole. Cagayanone was obtained from isosafrole in one step. The str uctures of the products were elucidated and the mechanism of their for mation is discussed.