SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW MU(2)-PHENOXY OXYGEN-BRIDGEDMACROCYCLIC BINUCLEAR CADMIUM(II) COMPLEX WITH PENDANT ARMS

Authors
XU XY LUO QH SHEN MC HUANG XY WU QJ
Citation
Xy. Xu et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW MU(2)-PHENOXY OXYGEN-BRIDGEDMACROCYCLIC BINUCLEAR CADMIUM(II) COMPLEX WITH PENDANT ARMS, Polyhedron, 16(6), 1997, pp. 915-919
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
6
Year of publication
1997
Pages
915 - 919
Database
ISI
SICI code
0277-5387(1997)16:6<915:SACOAN>2.0.ZU;2-4
Abstract
A new binuclear cadmium(II) macrocyclic complex has been synthesized b y [2+2] Schiff-base condensation of tris(3-aminopropyl) amine with sod ium 2,6-diformyl-4-methoxylphenolate in the presence of Cd(ClO4)(2) . 6H(2)O. The crystal structure, spectral characterization and molar con ductivity show that two cadmium(II) ions were bridged by two mu(2)-phe noxy oxygen atoms. Each cadmium(II) is located in a trigonal prismatic coordination environment N4O2). Copyright (C) 1996 Published by Elsev ier Science Ltd