In applying ac impedance to fuel cells and their porous (gas diffusion
) electrodes the emphasis lies on different fuel cell components, and
their properties, according to the fuel cell type. The focus has been
directed at the electrode/electrolyte interface in MCFC and PAFC, wher
eas in SOFC and PEMFC the ionic/electronic conductivity of the electro
lyte or the characteristics of its composite with the electrocatalyst
is of primary interest. The limitations of ac impedance in fuel cell a
pplication are in part due to difficulties of interpretation and in pa
rt due to experimental difficulties because of the generally fast elec
trode reaction kinetics. Further research directions are indicated.