We report evidence of an interference process between two bound-free a
tomic transitions induced by laser fields. Sodium atoms, initially pre
pared in the 3P(1/2) excited state, are ionized by a nonresonant three
-photon interaction with 1064-nm laser light and by a one-photon inter
action with the third-harmonic field, at 355 nm. Interference between
the two transition paths allows the control of the total ionization ra
te by varying the relative phase of the laser fields. The experiment h
as provided a fringe visibility as high as 42%.