OPTICAL NONLINEARITY OF DISTORTED CUBIC CAGE-SHAPED CLUSTER COMPOUNDS(MAG(3)S(3)[S2P(OCH2CH3)(2)])(S)(PH(3)P)(3) (M=W,MO)

Authors
WU XT WANG QM SHI S
Citation
Xt. Wu et al., OPTICAL NONLINEARITY OF DISTORTED CUBIC CAGE-SHAPED CLUSTER COMPOUNDS(MAG(3)S(3)[S2P(OCH2CH3)(2)])(S)(PH(3)P)(3) (M=W,MO), Polyhedron, 16(6), 1997, pp. 945-948
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
6
Year of publication
1997
Pages
945 - 948
Database
ISI
SICI code
0277-5387(1997)16:6<945:ONODCC>2.0.ZU;2-C
Abstract
The non-linear optical (NLO) properties of two distorted cage clusters {WAg3S3 [S2P(OCH2 CH3)(2)]}(S)(Ph(3)P)(3) (1) and {MoAg3S3[S2P(OCH2CH 3)(2)]}(S)(Ph(3)P)(3) (2) were studied. Both NLO absorption and refrac tion were observed with 1 and 2, third-order effects were detected wit h alpha(2) = 6 x 10(-10) mW(-1) for 1 and alpha(2) = 8 x 10(-10) mW(-1 ) for 2. NLO refraction was also found on 1 and 2, with n(2) = 1 x 10( -16) m(2) W-1 for 2. The non-linearity of these two clusters was compa red with some related NLO materials. Copyright (C) 1996 Elsevier Scien ce Ltd