M. Matecki et al., DEVITRIFICATION STUDIES OF HEAVY-METAL FLUORIDE GLASSES CONTAINING ALKALI FLUORIDE, Materials research bulletin, 28(10), 1993, pp. 997-1004
The devitrification on reheating of the BIGaZYbTM glasses (M : Li, Na,
K) was characterized using differential scanning calorimeter. Isother
mal and non-isothermal methods allowed the determination of the Avrami
's parameters, n situated between 2 - 4 and the apparent activation en
ergy E varying from 30 to 55 kcal/mol. These last values explain the e
xcellent stability of these glasses against crystallization.