The influence of post-growth low-temperature doping with Ga on the PL
properties of the p-CdTe bulk crystals have been investigated. It was
shown that during annealing in Ga-bath, the atoms of Ga incorporate in
to p-CdTe as Ga(Cd) donors. In crystals with Cu(Cd) and Li(Cd) as resi
dual acceptors, Ga atoms replace Cu and Li in Cd sites to form two sha
llow donors, Ga(Cd) and (Cu, Li)i per one atom of Ga. Comparisons of t
he Ga-annealing of p-CdTe with the annealing in vacuum, in Cd vapour a
nd in Hg-Te atmosphere have been made.