The elimination of mercury vapours from gaseous streams has been studi
ed using sulfurized silicates as adsorbents. A new method to sulfurize
the materials based in hydrogen sulfide oxidation at low temperature
is proposed. The sulfur produced in the reaction is deposited on the m
aterial, its dispersion depending on the process temperature and physi
co-chemical properties of the silicates used. The adsorbents were test
ed in static and dynamic systems for mercury depuration of gaseous str
eams. Commercial sulfurized active carbon was used as a reference. X-r
ay diffraction, atomic absorption spectroscopy, X-ray photoelectron sp
ectroscopy, nitrogen adsorption-desorption and mercury intrusion poros
imetry were used in raw materials and adsorbents characterization.