INTRAMOLECULAR AMIDOALKYLATION OF CHIRAL IMINIUM IONS - STEREOSELECTIVE SYNTHESIS OF SYN-1,3-AMINOALCOHOLS

Authors
HIOKI H OKUDA M MIYAGI W ITO S
Citation
H. Hioki et al., INTRAMOLECULAR AMIDOALKYLATION OF CHIRAL IMINIUM IONS - STEREOSELECTIVE SYNTHESIS OF SYN-1,3-AMINOALCOHOLS, Tetrahedron letters, 34(38), 1993, pp. 6131-6134
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
38
Year of publication
1993
Pages
6131 - 6134
Database
ISI
SICI code
0040-4039(1993)34:38<6131:IAOCII>2.0.ZU;2-U
Abstract
The intramolecular Hosomi-Sakurai reaction of 3-siloxybutaniminium sal ts exhibited a syn selectivity of up to 51:1, while the same type of r eaction of 2-methyl-3-siloxypropaniminium salts showed up to 290:1 syn selectivity.