ABOUT ORIGIN OF Q-COMPONENT ON THE VIBRATION-ROTATION BAND OF HF IN SIMPLE SOLVENTS

Citation
Kg. Tokhadze et Z. Mielke, ABOUT ORIGIN OF Q-COMPONENT ON THE VIBRATION-ROTATION BAND OF HF IN SIMPLE SOLVENTS, The Journal of chemical physics, 99(7), 1993, pp. 5071-5077
Citations number
47
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
99
Issue
7
Year of publication
1993
Pages
5071 - 5077
Database
ISI
SICI code
0021-9606(1993)99:7<5071:AOOQOT>2.0.ZU;2-O
Abstract
The evolution of the fundamental nu(HF) absorption in the spectra of H F/Ar, Xe, CO2, CO mixtures at densities varying from dilute gas to liq uid has been studied. The spectral region of the HF librational mode h as been simultaneously examined. The results show that molecular compl exes play the crucial role in the mechanism of formation of the Q comp onent in the spectra of HX in simple solvents.