H. Seto et al., A SMALL-ANGLE NEUTRON-SCATTERING STUDY OF DENSITY-FLUCTUATIONS AT NEAR-CRITICAL REGION AND A VAN-DER-WAALS MODEL IN A 3-COMPONENT MICROEMULSION, The Journal of chemical physics, 99(7), 1993, pp. 5512-5519
A small angle neutron scattering investigation near the critical point
of D2O/n-decane/AOT water-in-oil microemulsion was carried out. Altho
ugh the previous results in literature indicated the Ising behavior, t
he meanfield behavior for the susceptibility was observed. From the an
alysis of the susceptibility divergence, binodal point and spinodal po
int for each composition were given. In order to explain these points,
the Gibbs free energy of mixing with the Flory-Huggins interaction pa
rameter is introduced in the framework of the van der Waals model.