Optical and electrical measurements of GaAs layers grown by liquid-pha
se epitaxy with different amounts of Gd metal added to the Bi and Pb s
olutions are reported. The presence of Gd during growth causes suppres
sion of donor impurity-related luminescence bands due to the gettering
of donor impurities. Gadolinium gettering contributed to the reductio
n of the concentration of donors below the concentration of acceptors.
This gettering is driven by chemical reactions in the solution rather
than in the solid.