ON THE SYNTHESIS OF UNSYMMETRICAL BIS(MACROCYCLIC) LIGANDS

Citation
Jl. Sessler et Jw. Sibert, ON THE SYNTHESIS OF UNSYMMETRICAL BIS(MACROCYCLIC) LIGANDS, Tetrahedron, 49(39), 1993, pp. 8727-8738
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
49
Issue
39
Year of publication
1993
Pages
8727 - 8738
Database
ISI
SICI code
0040-4020(1993)49:39<8727:OTSOUB>2.0.ZU;2-X
Abstract
The syntheses of novel three and four carbon-bridged unsymmetrical bis (macrocyclic) ligands have been investigated. Suitable functionalizati on of a selectively protected 1,4,7-triazacyclononane macrocycle allow s for the coupling of this well-studied ligand to either 1,4-diazacycl ononane or 4,7-diaza-1-oxacyclononane.