SUGAR SENSING UTILIZING AGGREGATION PROPERTIES OF A BORONIC-ACID-APPENDED PORPHYRIN

Authors
MURAKAMI H NAGASAKI T HAMACHI I SHINKAI S
Citation
H. Murakami et al., SUGAR SENSING UTILIZING AGGREGATION PROPERTIES OF A BORONIC-ACID-APPENDED PORPHYRIN, Tetrahedron letters, 34(39), 1993, pp. 6273-6276
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
39
Year of publication
1993
Pages
6273 - 6276
Database
ISI
SICI code
0040-4039(1993)34:39<6273:SSUAPO>2.0.ZU;2-Y
Abstract
It was shown that monosaccharides can be sensitively detected utilizin g aggregation properties of a boronic-acid-appended porphyrin. Since t he magnitude of the spectral change is correlated with the association tendency between sugars and boronic acids, the origin of the spectral change is related to the increase in the hydrophilicity in the sugar- binding site.