GATED GLYOXIMES - CONFORMATIONALLY FLEXIBLE BORON-LINKED SUPERSTRUCTURE IN IRON (DIOXIMATO)BORATE COMPLEXES

Authors
STYNES DV LEZNOFF DB DESILVA DGAH
Citation
Dv. Stynes et al., GATED GLYOXIMES - CONFORMATIONALLY FLEXIBLE BORON-LINKED SUPERSTRUCTURE IN IRON (DIOXIMATO)BORATE COMPLEXES, Inorganic chemistry, 32(19), 1993, pp. 3989-3990
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
32
Issue
19
Year of publication
1993
Pages
3989 - 3990
Database
ISI
SICI code
0020-1669(1993)32:19<3989:GG-CFB>2.0.ZU;2-1
Abstract
Boron-linked groups are moved into or out of intimate contact with iro n-bound ligands via conformational flips of the boroxime chelate rings in Fe(DMGBR2)2 complexes, BR2 - BH2, BF2, BPh2, and BBN. Thermodynami c and kinetic consequences of the dynamic linkage between macrocycle c onformation and axial ligation to iron are described.