The preparation of polycrystalline GaAs films by using electrodepositi
on technology is described in this paper. Using scanning electron micr
oscopy, X-ray diffraction, spectrophotometry and capacitance voltage t
esting. we have measured the characteristics of the films prepared. Th
e results show that the stoichiometry of the film is Ga0.91As1.09. On
the basis of a Mott-Schottky plot, the position of the energy band edg
es of the film is calculated. Finally, the photoelectrochemical charac
teristic of the Ga0.91As1.09 film/electrolyte junction is measured.