GENERATION AND DRIFT OF PHOTOCARRIERS IN A CONJUGATED LADDER POLYMER

Citation
H. Antoniadis et al., GENERATION AND DRIFT OF PHOTOCARRIERS IN A CONJUGATED LADDER POLYMER, Synthetic metals, 60(2), 1993, pp. 149-157
Citations number
39
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
ISSN journal
03796779
Volume
60
Issue
2
Year of publication
1993
Pages
149 - 157
Database
ISI
SICI code
0379-6779(1993)60:2<149:GADOPI>2.0.ZU;2-2
Abstract
Generation and drift of photocarriers in thin films of the conjugated ladder polymer, poly(benzimidazobenzophenanthroline) (BBL), are explor ed by using transient photoconductivity methods. An estimation of a lo wer limit for photogeneration efficiency of mobile holes is found to b e close to 10(-2) at an electric field of 5 X 10(5) V/cm. The drift of photogenerated carriers is found to be severely range limited by trap ping events. In addition persistent decay of photocurrent is detected following the termination of a steady-state monochromatic illumination . The form of the persistent photocurrent suggests a broad range of re lease times of the trapped carriers which can be attributed to a disor der-induced distribution of trapping sites.