Generation and drift of photocarriers in thin films of the conjugated
ladder polymer, poly(benzimidazobenzophenanthroline) (BBL), are explor
ed by using transient photoconductivity methods. An estimation of a lo
wer limit for photogeneration efficiency of mobile holes is found to b
e close to 10(-2) at an electric field of 5 X 10(5) V/cm. The drift of
photogenerated carriers is found to be severely range limited by trap
ping events. In addition persistent decay of photocurrent is detected
following the termination of a steady-state monochromatic illumination
. The form of the persistent photocurrent suggests a broad range of re
lease times of the trapped carriers which can be attributed to a disor
der-induced distribution of trapping sites.