We have systematically investigated the doping effect on the Bi2Sr2Ca2
Cu3Oy superconductive material. After entering into the crystal lattic
e, Pb and/or Sb atoms cause not only variations of the temperature con
dition during the sample preparation process, but also variations of s
tructures and superconductivity. By analyzing the experimental results
, we have come to the conclusion that the Pb and/or Sb atoms enter int
o the Bi-O planes, preferably occupy the sites of Bi ions, regulate th
e crystal structures and the distribution of oxygen ions in Bi-O plane
s and nearby lattice sites, thus benefiting the formation of the high-
T-c phase and improving the superconductivity.