PHOTOSWITCHABLE CATENANES

Citation
F. Vogtle et al., PHOTOSWITCHABLE CATENANES, Angewandte Chemie, International Edition in English, 32(9), 1993, pp. 1295-1297
Citations number
25
Categorie Soggetti
Chemistry
ISSN journal
05700833
Volume
32
Issue
9
Year of publication
1993
Pages
1295 - 1297
Database
ISI
SICI code
0570-0833(1993)32:9<1295:PC>2.0.ZU;2-A
Abstract
A reversible mechanical control of the mobility of the interlocked rin gs is possible in photoswitchable catenanes like 1. Furthermore, the c rown ether guest influences the thermal isomerization of the azobenzen e host: the catenane 1 isomerizes ten times faster than the unoccupied host macrocycle from the (Z) to the (E) configuration.