INTRAMOLECULAR BASE STABILIZATION OF SILICENIUM IONS - A NEW ROUTE TOSILICONIUM IONS

Authors
CHUIT C CORRIU RJP MEHDI A REYE C
Citation
C. Chuit et al., INTRAMOLECULAR BASE STABILIZATION OF SILICENIUM IONS - A NEW ROUTE TOSILICONIUM IONS, Angewandte Chemie, International Edition in English, 32(9), 1993, pp. 1311-1313
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
9
Year of publication
1993
Pages
1311 - 1313
Database
ISI
SICI code
0570-0833(1993)32:9<1311:IBSOSI>2.0.ZU;2-D
Abstract
The silicon atom is pentacoordinate in cations of salts like 1, which can be prepared, for instance, in a redox reaction of the correspondin g silane (with I2, X = I) or transformation with electrophiles like Ph COCl (X = Cl) or Ph3C+BF4- (X = BF4). These compounds were completely characterized; conductivity titrations confirm that they are ionic.