THE 1ST TRIGONAL-BIPYRAMIDAL CLUSTER WITH AN INTERSTITIAL C2 UNIT - [RB(PR5(C2))CL10]

Authors
MEYER G UHRLANDT S
Citation
G. Meyer et S. Uhrlandt, THE 1ST TRIGONAL-BIPYRAMIDAL CLUSTER WITH AN INTERSTITIAL C2 UNIT - [RB(PR5(C2))CL10], Angewandte Chemie, International Edition in English, 32(9), 1993, pp. 1318-1319
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
9
Year of publication
1993
Pages
1318 - 1319
Database
ISI
SICI code
0570-0833(1993)32:9<1318:T1TCWA>2.0.ZU;2-6
Abstract
Nine Cl atom bridge the edges of the compressed trigonal bipyramid (st abilized by the incorporated carbon pair) of the central [{Pr5(C2)}(Cl 21)] unit of the title compound (picture on the right). In addition th ree terminal Cl atoms bind to each apex of the bipyramid and two each to the Pr atoms of the pyramidal base. Till now only tetrahedral and o ctahedral clusters of metal-rich lanthanide halides were known.