STRUCTURE AND ELECTROCHEMICAL-BEHAVIOR OF THE PARAMAGNETIC ANION [IR14(CO)27]-, POSSESSING A TRIGONAL BIPYRAMIDAL ARRANGEMENT OF METAL ATOMS

Authors
DELLAPERGOLA R GARLASCHELLI L MANASSERO M MASCIOCCHI N ZANELLO P
Citation
R. Dellapergola et al., STRUCTURE AND ELECTROCHEMICAL-BEHAVIOR OF THE PARAMAGNETIC ANION [IR14(CO)27]-, POSSESSING A TRIGONAL BIPYRAMIDAL ARRANGEMENT OF METAL ATOMS, Angewandte Chemie, International Edition in English, 32(9), 1993, pp. 1347-1349
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
9
Year of publication
1993
Pages
1347 - 1349
Database
ISI
SICI code
0570-0833(1993)32:9<1347:SAEOTP>2.0.ZU;2-K
Abstract
The structure hardly changes when the cluster [Ir14(CO)27]- (1) is red uced to the dianion or oxidized to the neutral compound. The 14 Ir ato ms form a trigonal bipyramid, which contains an Ir atom at the center of every edge (see picture). The terminal CO ligands cover the metal f ramework completely.