Ma. Hines et al., RAMAN STUDIES OF STERIC HINDRANCE AND SURFACE RELAXATION OF STEPPED H-TERMINATED SILICON SURFACES, Physical review letters, 71(14), 1993, pp. 2280-2283
Polarized, angle-resolved Raman spectra of the Si-H stretching vibrati
ons on stepped H-terminated Si(111) surfaces confirm the constrained o
rientation of the step dihydride derived from ab initio cluster calcul
ations. They further show that the step normal modes involve little co
ncerted motion of the step atoms, indicating that step relaxation redu
ces the steric interaction much further than predicted.