W. Engel et al., APPLICATION OF TIME AND TEMPERATURE RESOLVED X-RAY-DIFFRACTION (TRXRD) TO THERMAL-ANALYSIS, Journal of thermal analysis, 40(3), 1993, pp. 1017-1024
The application of TRXRD for thermal analysis is demonstrated using ex
amples of phase transitions, solid-state reactions and high-temperatur
e corrosion. The measuring system produces a series of diffraction pat
terns, which are evaluated by a difference procedure that a reduces th
e data to curves comparable to DSC and TG curves and thus suited to ki
netic evaluation.