Mossbauer spectroscopy has been used to investigate the solid phase tr
ansformation of goethite into hematite at 250-degrees-C. An Avrami-Ero
feyev-type relation was found to describe the thermal conversion of al
pha oxihydroxide to the alpha iron oxide. No intermediate phase was ob
served in the analyzed samples. The reaction constant was determined.
A possible nucleation mechanism is also discussed.